Directed by Don Kempf, James D. With Michael Jordan, Phil Jackson, Doug Collins, Bob Greene. Follow the latest updates about Media on SLAMonline. Lonzo Ball, NBA draft prospect, deserves $1 billion deal. Alternative facts. EVERYONE wants a piece of potential 2. NBA Draft No. 1 pick Lonzo Ball — but he doesn’t come cheap and he comes with some baggage. His old man La. Var Ball is the closest thing to the textbook dysfunctional tennis father the NBA has right now. Forget what you thought you knew about basketball and, if you dare, take a step into the mind of Mr Ball. Former American professional basketball player, active businessman, and majority owner of the Charlotte Bobcats, Michael Jordan has an estimated net worth. Bienvenue sur le site de. SOCIÉTÉ ROSE BLEUE. Tel: 06 27 78 09 41 Grossiste Destockeur spécialisé dans les produits de Grandes marques. The ultimate source for self confidence, personal achievement, and a powerful mindset. Focusing on seasonal ingredients, pure bold flavors, and authentic hospitality, we elevate the classic steak house experience to the Michael Jordan level. The outspoken parent has been the talk of basketball circles in recent weeks for his outlandish claims and predictions surrounding his talented trio of sons. If La. Var’s optimism is anything to go by his sons Lonzo, Li. Angelo (a high school senior committed to UCLA) and La. Melo (a high school sophomore also committed to UCLA) are transcendent talents about to revolutionise basketball. Now he’s dropped his biggest whopper yet. La. Var is holding apparel giants Nike, Adidas and Under Armour to ransom, refusing to sign Lonzo to a sneaker ambassador deal on his own. La. Var wants one of the basketball shoe giants to cough up $1 billion to sign his three sons in a bulk deal never seen before. You can’t have one without the other two. Lonzo Ball is a future superstar. While wars, diseases and.Source: AFPTo give La. Var’s evaluation some context, Aussie Ben Simmons, the No. NBA Draft, last year signed a five- year shoe deal with Nike reportedly worth $1. It means La. Var reckons his eldest son is worth roughly 5. Right now, La. Var has the pick of the litter with his son Lonzo credited for UCLA’s impressive season which has seen the school handed the No. South Region bracket for the NCAA March Madness college basketball national championships. He’s taking full advantage of his situation.“A billion dollars, it has to be there,” Ball told usatoday. Tuesday.“That’s our number, a billion, straight out of the gate. And you don’t even have to give it to me all up front. Give us $1. 00 million over 1. He’s a generous guy. He’s also completely delusional. Le. Bron James signed the richest shoe deal in basketball last year — a lifetime deal with Nike that was initially reportedly worth $5. Months later James’ business partner hinted the true value of the deal is closer to $1 billion. However, King James has four NBA MVP trophies to his name and three championships. La. Var and his boys have never played in the NBA. Daddy’s got your back. Source: AFPLonzo is undoubtedly a future star, but his old man may cost him the top pick in this year’s draft, according to NBA commentators. NBA legend Charles Barkley this week labelled La. Var’s outspokenness “stupidity”. It came after La. Var claimed his son Lonzo is a better player than NBA MVP Steph Curry.“You can’t say a guy is going to be better than Steph Curry, a guy who has played 3. Barkley said.“I know you can be proud of your son, but at some point, it becomes stupidity.”Incredibly, La. Var Ball’s Curry declaration is not even close to the most idiotic thing he has said this week. He has claimed Lonzo would immediately transform the Los Angeles Lakers into a playoff team — if the Lakers secure the No. He also reckons Lonzo could easily become a better player than Michael Jordan. Yep, Michael Jordan. While speaking about His Royal Airness, it’s important to note too that La. Var reckons he would have carved up the Chicago Bulls megastar one- on- one.“Back in my heyday, I would kill Michael Jordan one- on- one,’’ Ball said. That’s a helluva place to be coming from.
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Browse All Poems - Love Poems. Thou, who dost dwell alone; Thou, who dost know thine own; Thou, to whom all are known.... Archives - Philly. Find showtimes, watch trailers, browse photos, track your Watchlist and rate your favorite movies and TV shows on your phone or tablet! Get breaking news and the latest headlines on business, entertainment, politics, world news, tech, sports, videos and much more from AOL. Another of Stephanie as April Dancer in Girl from UNCLE for those here into tape gags. Also, for the record, I am NOT into any kind of bug or insect or any other kind. If you find one, click here: ADD WEBSITE: Paws of VaIor AnimaI Rescue was founded to heIp dogs and cats in need in East Tennessee. Short Term Awards for QSOs in 2015. Contacts for awards on this page must be made generally during the calendar year 2015. Some of the award periods may range from as. The following is a list of events affecting American television in 2015. Events listed include television show debuts, finales, and cancellations; channel launches. By Tristan McConnell. We do not log traffic or session data of any kind, period. We have worked very hard to craft the specialized technology we use to safeguard your privacy. What that means is he has never lived in a home before and he is very under. Alienate (2. 01. 6) - IMDb. Edit. At the end of his marriage, David leaves on a business trip to give his wife much- needed space. When airplanes start mysteriously falling out of the sky and cell towers fail across the nation, he finds himself trapped. The Earth falling to an alien invasion, David fights to return to whatever is left of home. Social alienation is "a condition in social relationships reflected by a low degree of integration or common values and a high degree of distance or isolation between. Watch Alienated On 123movie, The movie focuses on an already splitting-at-the-seams couple, and their infinite inability to resolve their rapport with one another. Alienated Labor Karl MarxSynonyms for alienated at Thesaurus.com with free online thesaurus, antonyms, and definitions. Dictionary and Word of the Day. The voices of adults who were alienated as children, revealed in the professional literature and observed in my research and experience over three decades with more. Books Title: Alienated. Two years ago, the aliens made contact. Now Cara Sweeney is going to be sharing a bathroom with one of them. Handpicked to host the first-ever. Stoffen spektakel @ LUXEXPO THEBOXSelf- made things are always something special and unique. Everything you need is an idea, a cut, the fabric and other accessories such as buttons, zippers, thread, etc. INTERNATIONAL TATTOO CONVENTION « THE STORM » 19 mai. En savoir + ING Night Marathon Luxembourg. Light in the box Fondé en 2006, lightinthebox est un distributeur international sur Internet d’articles issus du marché chinois au tarif de gros, quelque soit le. Note: There will also be a $1 PayPal charge for online payments. Some specialty Boxes have an additional charge. Opportunities Out Of The Box Installations is comprised of a core group having been in the industry for greater than 20 years each. First and foremost is TECH. With more than 4. Stoffen Spektakel market provides the most extensive range of fabrics. Stoffenspektakel is organized in Hall 7 at LUXEXPO THE BOX. Food is available on site. Access: South & North Entrance. ORGANISERM Julian Timmermaninfo@stoffenspektakel.
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Kate is a perceptive and determined character, and being inside her head while she makes deductions and analyzes her targets is an enormous amount of fun. Even more enjoyable is the way Kate wrangles her new detective colleagues, most of whom are varying degrees of sexist and some of whom have surprising hidden depths. Stories Untold WalkthroughWatch Untold Stories Of The E.R. Online: Watch full length episodes, video clips, highlights and more. We are a collective of storytellers from across Asia on a mission to discover and tell untold stories, passionately. HitFix takes a deep dive into the iconic 'Johnny. B Goode' scene in 'Back to the Future,' detailing how the scene was written and shot, behind-the-scenes stories, and. Stories Untold Tv TropesWe all love books about queens and iconic artists, but historical fiction can also uncover the untold stories of history—from lady detectives to aspiring. Explore the true stories of America's covert operations told firsthand by the agents who lived it, while getting unprecedented access to the riveting and secret world. UNTOLD STORY section - vnafmamn.com You are viewing the first Untold Story, "VINH BIET SAIGON" (Farewell Saigon). The original version of the story about the VNAF. Untold Stories of the ER is an inside look at some the craziest stories and cases to enter an emergency room. Our Stories Untold is a blog dedicated to sharing stories about sexual violence and rape in both the Mennonite Church and all spiritual communities. Macallister wrings a great deal of tension out of the various setups and traps the Pinkerton detectives use to ferret out crime and sedition, at times simply by adhering to the restrictions of the detective work of the period. The story is episodic at first, allowing the reader and Kate to bounce from case to case while Macallister fleshes out the world of pre- Civil War America and expertly darkens the mood of the book. Once war breaks out, Kate and her colleagues are devoted to the Union war effort and Macallister’s carefully laid groundwork pays off. The shift from hunting down criminals to facing off against Confederate spies (one of whom is a clever mirror image of Kate herself) raises the stakes of the book and forces Kate into closer quarters with her colleagues and boss, setting up the characters for a satisfying series of confrontations. Long- simmering quarrels come to a head and an unexpected romance blooms that is both touching and maturely sexy. Steeped in the details of the period, Girl in Disguise is an entertaining ride as well as an homage to a brilliant woman who found and seized her chance at a life full of adventure and purpose. BOHEMIAN RHAPSODYThe inspiration for Edvard Munch’s The Scream is often said to be the artist’s own existential angst and possible mental illness. In The Girl Between, Lisa Str. The Girl Between is nominally the story of a love affair between two people, but truly the story of an emotional affair between three people. Johanne, who has grown up in the seaside town where Edvard lives and Tullik visits, is an aspiring artist herself as well as a girl just starting to question the boundaries and mores of her conservative upbringing. Johanne’s own artistic talent and burgeoning sense of her own desires color the entire novel, bursting forth in impressionistic passages that connect her emotions and sensations to the art she creates. Her vivid senses of the world around her, brought to startling life by Str. In The Girl Between, the boundary between the everyday world and the world of art and iconography is porous, with emotion, inspiration and passion constantly flowing from one character to another. Tullik is an especially fascinating figure as she is painfully aware of the limitations imposed on her because of her wealth and gender. She regresses into a childlike state as often as she attempts to be a bohemian firebrand. Because she is only ever viewed through Johanne’s eyes, it is unclear whether the fascination she provokes in others is entirely unconscious or carefully cultivated, whether her seduction of Edvard is a genuine meeting of souls or a frantic grasp for freedom. Johanne may pity and often idealize the lovers, but Str. Her name was Betty Cooper, and she disappeared for 2. Michael Callahan uses her story as a template for The Night She Won Miss America, set in 1. Miss Delaware Betty Welch, who only enters the competition to please her mother. Once in Atlantic City for the final days of competition, Betty find herself more interested in her dashing escort Griff than vying for the crown. But Griff isn’t exactly the picture- perfect suitor Betty thinks he is. Callahan masterfully creates the sparkling world of Atlantic City in the 5. Miss America pageant. From the lingo to the elaborate wardrobes of the contestants to the nightclubs and cocktails they frequent, his infectious enthusiasm for the period enlivens every page. Thankfully, he doesn’t rely solely on the delicious window dressing and provides the reader with two well- drawn main narrators—the innocent but self- possessed and intelligent Betty, and her more world- wise roommate Ciji. Betty is a keen, dubious observer of the pageant, whose increasing success in the competition mainly comes from her refusal to play the part of ambitious beauty queen. But when she meets and falls madly in love with Griffin Mc. Allister, her good sense wars with her powerful attraction to her escort. Callahan does a superb job at evoking the sweep and rush of first love, while at the same time undercutting the fantasy as Betty’s skeptical nature refuses to allow her to fully relax into Griff’s affections. Ciji, who only entered the pageant because she sees it as a stepping- stone to Hollywood, takes over sections of the narrative once the pageant is over and the strain of the real world sets in. A beauty queen with the cynicism of Humphrey Bogart, Ciji moves through the world with the ever- present knowledge that her good looks are a useful tool (up to a point). As Betty and Griff’s relationship darkens, Ciji finds herself torn between helping her friend and acting in her own best interests. The drama that unfolds is like one of the movies Ciji hopes to star in. Callahan nimbly guides the reader from the rounds of the Miss America competition to Times Square to a climax on a seaside cliff during a masquerade ball. The Night She Won Miss America is a delightfully dramatic and fast- paced summer read, with just the right amount of darkness to balance out the fluff. Stories - Our Stories Untold. Harry Styles joins 'Carpool Karaoke'Chat with us in Facebook Messenger. Find out what's happening in the world as it unfolds. Harry Styles gets emotional during 'Carpool Karaoke' jam session. Story highlights. Harry Styles sang several of songs off his debut solo album on . The former One Direction star has been co- hosting . They went on to sing Styles' other songs off his debut solo album, including. Carpool Karaoke is a recurring segment on The Late Late Show with James Corden in which James Corden, the host of the show, invites famous musical guests. While home in London for the holidays, James Corden picks up his friend Adele for a drive around the city singing some of her classic songs before Ade. Victoria Beckham and James Corden put a hilarious new spin on “Carpool Karaoke” on Thursday’s Late Late Show! THE LATE LATE SHOW with JAMES CORDEN throws the ultimate late night after party with a mix of celebrity guests, edgy musical acts, games and sketches. Every single time James Corden delivers another "Carpool Karaoke" session on the Late Late Show, it makes our day. It all started with an epic Mariah.Stream Preachers Son, a playlist by YGTUT from desktop or your mobile device. See the full list of The Preacher's Son cast and crew including actors, directors, producers and more. E Living Sacrifice Tut. Genres Hip Hop, Contemporary Hip Hop. Facebook. To help personalize content, tailor and measure ads, and provide a safer experience, we use cookies. By clicking or navigating the site, you agree to allow our collection of information on and off Facebook through cookies. Learn more, including about available controls: Cookies Policy. But where Rashad’s Cilvia Demo from last year appeared lost with its place in the world, Preacher’s Son knows where it stands within the church aisles. Irish rock band led Brian Hogan alongside a collective of mighty guests musicians A grit-glam, blues-tinged, swamp-rock sound with craggy guitars. The Preacher's Son is the fourth studio album released by rapper Wyclef Jean. The album was released on November 4, 2003. The album is produced by Jean and Jerry. The Preacher's Son (2017) cast and crew credits, including actors, actresses, directors, writers and more. Matthew Cooper, Executive Chef. Matthew’s passion for culinary art stems from its ability to bring people together. His style of cooking is rustic and traditional. The presence of whoever or whomever indicates a dependent clause. Use whoever or whomever to agree with the verb in that dependent clause, regardless of the rest of the sentence. Examples: Give it to whoever/whomever asks for it first. He asks for it first. Therefore, whoever is correct. We will hire whoever/whomever you recommend. You recommend him. Therefore, whomever is correct. We will hire whoever/whomever is most qualified. He is most qualified. Therefore, whoever is correct. Rule 2. When the entire whoever/whomever clause is the subject of the verb that follows the clause, look inside the clause to determine whether to use whoever or whomever. Examples: Whoever is elected will serve a four- year term. Whoever is the subject of is elected. The clause whoever is elected is the subject of will serve. Whomever you elect will serve a four- year term. Whomever is the object of elect. Whomever you elect is the subject of will serve. A word to the wise: Whomever is even more of a vogue word than whom. Many use it indiscriminately to sound cultured, figuring that no one will know any better.
To determine whether to use whoever or whomever, here is the rule: him/ he equals whoever, him/ him equals whomever.New International Version For whoever wants to save their life will lose it, but whoever loses their life for me will save it. New Living Translation. New International Version For whoever wants to save their life will lose it, but whoever loses their life for me will find it. New Living Translation. Amazon.com: Whoever You Are (Reading Rainbow Books) (8601404297175): Mem Fox, Leslie Staub: Books. Surface Tension Tutorial - Sensa. Dyne Instrument Division. Dynamic Surface Tension Measurement Tutorial DYNAMIC FINGERPRINTS OF FORMULATIONS USING SURFACE TENSION MEASUREMENTA unique dynamic fingerprint of any formulation can be generated in terms of surface tension versus surface age, from zero time to several minutes, using a differential maximum bubble pressure technique. This allows formulators and users to characterize formulation performance under all possible conditions before it is used. When multiple surfactants are used, the unique surface tension fingerprint may not be a “classical” dynamic curve, as different surfactants may diffuse to the interface at different rates, resulting in a complex dynamic curve with several peaks and valleys. In some cases, the lowest surface tension formulation may not be the best one to use because it can cause other problems. THE MOLECULAR DYNAMIC SURFACE TENSION FINGERPRINTEach fluid or formulation has a unique molecular fingerprint that is the tangential intermolecular force that keeps the fluid or formulation together, expressed in Dynes/Centimeter (or milli. Newtons/Meter). This parameter is the Fluid Surface Tension; the force that keeps the fluid together at any air/fluid interface. It is the intermolecular force of attraction between adjacent molecules, expressed in force per unit width. Water, at ambient temperature, has a high surface tension in the range of 7. Dynes/Cm. Solvents, typically, are in the 2. Dynes/Cm. If a simple pure fluid, or very complex formulation, changes at the molecular level then the fluid surface tension will change. We just have to measure it to see how the fingerprint has changed. Pure fluids and pure solvents have a single surface tension value called “static” or “equilibrium” surface tension. If the formulation contains surfactants, then it will have a “dynamic” surface tension. This dynamic surface tension varies as the surface age varies; essentially a dynamic “fingerprint” of surface tension versus surface age; surface age being the amount of time the process allows surfactant molecules in solution to migrate to any newly created air/fluid interface, where their purpose is to lower the surface tension. Since we are able to measure this molecular fingerprint, we can therefore use it to measure, in real time, whether formulation changes are taking place and to what degree. THE IMPORTANCE OF DYNAMIC SURFACE TENSION IN FORMULATIONSSurface tension dictates whether a formulation will wet and spread over, or retract from, a solid substrate. Any formulation exhibits both an adhesive force that is a measurement of the degree of association of the formulation for the substrate, and a cohesive force that is a measure of the degree of self- adhesion of the formulation. Spreading coefficient is the difference between work of adhesion and work of cohesion. If work of adhesion is greater than work of cohesion then spontaneous spreading occurs. If work of cohesion is greater than work of adhesion, then retraction occurs as the formulation will preferentially associate with itself. It is quite useful, and often very essential, that formulators have a good understanding of the principles and relationships of surface tension, and surface energy or “wetting tension”. Theymust control fluid transfer and adhesion by developing formulations that perform well under widely varying application speeds and operating conditions. There are factors that can be controlled, and others that cannot be controlled. A review of these important principals and relationships, with a brief introduction to formulation variables, will reinforce the knowledge that it takes to mitigate or entirely avoid problems. Solvent- based formulations, with their naturally lower surface tensions, wet readily and transfer well onto most substrates, even though they may have higher coefficients of spreading on select substrates. The increasing shift to water- based formulations, due to environmental concerns, has inherent problems of surface wetting, foaming, flow and leveling, common to all water- based systems. Surface Tension Of LiquidsSurface tension is the elastic tendency of a fluid surface which makes it acquire the least surface area possible. Surface tension allows insects (e.g. Today’s Wonder of the Day was inspired by Koenig Class from Arlington Heights, IL. Koenig Class Wonders, “What is surface tension and how does it work? Surface tension is an effect where the surface of a liquid is strong. The surface can hold up a weight, and the surface of a water droplet holds the droplet together. Main Entry: surface tension Function: noun: the attractive force felt by surface molecules of a liquid from the molecules beneath that tends to draw the surface. Gather up some spare change for this drops of water on a coin surface tension experiment! An easy science experiment for kids with a free printable chart. For those of you who may not know, Surface Tension Uncut was my little project to revamp Black Mesa's Surface Tension chapter. Black Mesa's recreation of this chapter. This video supplements content in the text, Chemistry and Physics for Nurse Anesthesia, Second Edition, by. Water- based formulations require alcohols and surfactants to lower their surface tensions to acceptable levels for transfer, spreading and adhesion. Spraying, spreading, dipping or applying in any other manner a fluid on a substrate is a dynamic process, and active surfactants cause surface tensions to change as speeds and formulations change. Surfactant activity directly impacts coating, spreading, and adhesion. Surface tension of formulations must be lower than the wetting tension of substrates to attain good wetting, printability, adhesive bondability, or formulation lay down. The physical properties of handling and mixing systems, to a large degree, are fixed and uncontrollable. Many facilities suffer the uncontrollable effects of seasonal changes; hot summer versus cold winter environments, for example. The cohesive forces between liquid molecules are responsible for the phenomenon known as surface tension. The molecules at the surface do not have. Processed solutions can and often do change at the formulation site, and change even more just prior to, and during, application. What is often formulated and tested in the laboratory is not what is ultimately used during application. Alcohols and reagents are lost to evaporation, and these losses can go undetected unless testing can be done at formulation and process sites. When any formulation is applied, surfactant molecules in the bulk solution react by diffusing to the interface. It is at this interface that the surfactant molecules try to line up with their hydrophobic ends pointed at the interface and the surface tension is lowered. The concentration and nature of the surfactant determines by how much the surface tension can be reduced, but the speed at which diffusion takes place influences how fast wetting will occur. Wettability, and ultimately “coatability”, is influenced by the combined physical and chemical properties of the constituents. It is this area of controllable factors that we briefly examine, with emphasis on techniques used to measure the dynamic surface tension of formulations. Surfactants are utilized and found in many fluid formulations because of their ability to reduce the surface tension in water- based and solvent- based systems. In some industrial applications they are even added for emissions reduction purposes, as defoaming agents to mitigate hazardous degassing. In many industrial cleaning formulations, for example, surfactants are added since they boost cleaning effectiveness and aid in wetting and defoaming. In inks, fountain solutions, adhesives, and coatings, surfactants are added to lower the surface tension below the surface energy of the substrate to be coated in order to obtain a positive spreading coefficient that enhances wetting, spreading and adhesion. The surfactant molecules then begin to diffuse to, and adsorb at, the newly created fluid/ substrate interface and the fluid/air interface. It takes a finite amount of time for the surface tension to reach equilibrium, anywhere from several seconds to several minutes. This is why the relevant parameter in designing formulations is dynamic surface tension rather than static (also know as equilibrium) surface tension. Anionic surfactants have a negative molecular charge, cationics positive, and nonionics no charge. In amthoterics there are both positive and negative charges. Anionics and nonionic surfactants provide most of industrial surfactant requirements and are the most common. Selection of surfactants is based on specific needs and often mixed surfactants are used which result in the afore- mentioned “complex” dynamic surface tension fingerprints. Most surfactants at higher concentrations exert strong molecular attractions between adjacent molecules causing strong surface films, the strength of which determines the surface properties of the surfactant solutions. Nonionic surfactants with ethylene oxide groups usually diffuse very rapidly to the surface while fluorinated surfactants are slower and more effective at equilibrium. For example, surfactants that diffuse slowly may not lower surface tensions sufficiently, within dynamic coating time constraints to acceptable levels and may be partially responsible for defects such as: b. Both rheology and surface tension modifications are used to reduce or eliminate surface defects. Increasing the viscosity can eliminate retraction, for example, but if a viscosity increase is not viable, then the formulator may have to address defect reduction through surfactant modification. A rapidly diffusing surfactant can mitigate surface defects, by eliminating surface tension gradients. This occurs through rapid surfactant migration from high concentrations (low surface tension) to low concentrations (high surface tension). Formulators will sometimes mistakenly increase surfactant concentration in order to reduce gradients, rather than use a better surfactant. This can result in higher surfactant costs and other problems. A surfactant having both low equilibrium and dynamic surface tension in water may not necessarily have the same characteristics in a highly formulated system. Extra surfactant can become “tightly bound” with polymeric binders, or can be solubalized with pigment micelles, becoming ineffective in producing further surface tension reduction. Some classes of surfactants have rapid diffusion characteristics because of unique polar molecular structures. This type of surfactant is capable of reducing surface tension with the extra benefit of reducing or preventing foam. With a hydrophobe- hydrophile- hydrophobe structure which displaces materials that form solid structural films at the interface, they make excellent wetting agents or surface tension reducers. These acetylenic diol- based surfactants have highly- branched alkyl groups and are horizontally, rather than vertically, adsorbed at the air/liquid interface. At low concentrations, these molecules cover large areas, but can be squeezed together as the concentration increases, exhibiting a unique compressible nature. |